If you are simply commuting, then the answer is no. However, if your employer requested you to do a specific task on your way to or from work, and you are injured while doing so (ie, car accident), then you may pursue work comp benefits as you would be “in the course and scope of your employment”.
These cases hinge on the specific facts and it is important to get a full analysis from an experienced PA work comp lawyer.
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Michael W. Cardamone Experienced PA Work Comp Lawyer